arXiv:cond-mat/0506583 Abstract

arXiv:cond-mat/0506583Abstract References Reviews Resources

Quantum tunneling of magnetization in lanthanide single-molecule magnets, bis(phthalocyaninato)terbium and bis(phthalocyaninato)-dysprosium anions

Published 2005-06-22Version 1

Magnetization versus field measurements were performed on single crystals of [(Pc)2TbIII0.02YIII0.98]^TBA+ and [(Pc)2DyIII0.02YIII0.98]^TBA+ (Pc: phthalocyaninato, TBA: tetrabutylammonium) at 0.04 K. The [(Pc)2TbIII] complex, the first lanthanide single-molecule magnet, exhibited clear staircase-like structures, which are assigned to resonant quantum tunneling between entangled states of the electron and nuclear spin systems.

Comments: Received: November 17, 2004, Revised: February 15, 2005; Published online: April, 2005

Journal: Angew. Chem. Int. Ed. 44, 2931 (2005)

DOI: 10.1002/anie.200462638

Categories: cond-mat.mes-hall, cond-mat.mtrl-sci

Keywords: phthalocyaninato, quantum tunneling, magnetization, first lanthanide single-molecule magnet, nuclear spin systems

Tags: journal article

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