{ "id": "cond-mat/0506583", "version": "v1", "published": "2005-06-22T20:57:41.000Z", "updated": "2005-06-22T20:57:41.000Z", "title": "Quantum tunneling of magnetization in lanthanide single-molecule magnets, bis(phthalocyaninato)terbium and bis(phthalocyaninato)-dysprosium anions", "authors": [ "N. Ishikawa", "M. Sugita", "W. Wernsdorfer" ], "comment": "Received: November 17, 2004, Revised: February 15, 2005; Published online: April, 2005", "journal": "Angew. Chem. Int. Ed. 44, 2931 (2005)", "doi": "10.1002/anie.200462638", "categories": [ "cond-mat.mes-hall", "cond-mat.mtrl-sci" ], "abstract": "Magnetization versus field measurements were performed on single crystals of [(Pc)2TbIII0.02YIII0.98]^TBA+ and [(Pc)2DyIII0.02YIII0.98]^TBA+ (Pc: phthalocyaninato, TBA: tetrabutylammonium) at 0.04 K. The [(Pc)2TbIII] complex, the first lanthanide single-molecule magnet, exhibited clear staircase-like structures, which are assigned to resonant quantum tunneling between entangled states of the electron and nuclear spin systems.", "revisions": [ { "version": "v1", "updated": "2005-06-22T20:57:41.000Z" } ], "analyses": { "keywords": [ "phthalocyaninato", "quantum tunneling", "magnetization", "first lanthanide single-molecule magnet", "nuclear spin systems" ], "tags": [ "journal article" ], "note": { "typesetting": "TeX", "pages": 0, "language": "en", "license": "arXiv", "status": "editable" } } }