Vipin P, R. Sankaranarayanan
Published 2020-08-04Version 1
van't Hoff equation relates equilibrium constant of a chemical reaction $K$ to temperature $T$. Though the van't Hoff plot ($\ln K$ vs $1/T$) is linear, the plot is nonlinear for certain chemical reactions. In this work we attribute such observations to virial coefficients.
Comments: 7 pages, 5 figures
Universal dynamic scaling in chemical reactions at and away from equilibrium
On analytical formulas for the Virial coefficients
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