{ "id": "2008.01751", "version": "v1", "published": "2020-08-04T18:13:26.000Z", "updated": "2020-08-04T18:13:26.000Z", "title": "Role of virial coefficients in chemical reaction", "authors": [ "Vipin P", "R. Sankaranarayanan" ], "comment": "7 pages, 5 figures", "categories": [ "cond-mat.stat-mech", "physics.chem-ph" ], "abstract": "van't Hoff equation relates equilibrium constant of a chemical reaction $K$ to temperature $T$. Though the van't Hoff plot ($\\ln K$ vs $1/T$) is linear, the plot is nonlinear for certain chemical reactions. In this work we attribute such observations to virial coefficients.", "revisions": [ { "version": "v1", "updated": "2020-08-04T18:13:26.000Z" } ], "analyses": { "keywords": [ "chemical reaction", "virial coefficients", "vant hoff equation relates equilibrium", "hoff equation relates equilibrium constant", "vant hoff plot" ], "note": { "typesetting": "TeX", "pages": 7, "language": "en", "license": "arXiv", "status": "editable" } } }