Thermodynamic equilibrium and its stability for Microcanonical systems described by the Sharma-Taneja-Mittal entropy

A. M. Scarfone, T. Wada

Published 2005-04-05, updated 2005-09-06Version 2

It is generally assumed that the thermodynamic stability of equilibrium state is reflected by the concavity of entropy. We inquire, in the microcanonical picture, on the validity of this statement for systems described by the bi-parametric entropy $S_{_{\kappa, r}}$ of Sharma-Taneja-Mittal. We analyze the ``composability'' rule for two statistically independent systems, A and B, described by the entropy $S_{_{\kappa, r}}$ with the same set of the deformed parameters. It is shown that, in spite of the concavity of the entropy, the ``composability'' rule modifies the thermodynamic stability conditions of the equilibrium state. Depending on the values assumed by the deformed parameters, when the relation $S_{_{\kappa, r}}({\rm A}\cup{\rm B})> S_{_{\kappa, r}}({\rm A})+S_{_{\kappa, r}}({\rm B})$ holds (super-additive systems), the concavity conditions does imply the thermodynamics stability. Otherwise, when the relation $S_{_{\kappa, r}}({\rm A}\cup{\rm B})<S_{_{\kappa, r}}({\rm A})+S_{_{\kappa, r}}({\rm B})$ holds (sub-additive systems), the concavity conditions does not imply the thermodynamical stability of the equilibrium state.