Structure and dynamics investigations of a partially hydrogenated graphene/Ni(111) surface

Emanuel Bahn, Anton Tamtögl, John Ellis, William Allison, Peter Fouquet

Published 2022-12-14Version 1

Using helium-3 atom scattering, we have studied the adsorption kinetics, the structure and the diffusional dynamics of atomic hydrogen on the surface of a graphene monolayer on Ni(111). Diffraction measurements reveal a 4$^\circ$ rotated rectangular hydrogen overstructure. Hydrogen adsorption and desorption exhibit activation barriers of $E_a=(89\pm7)\,$meV and $E_d=(1.8\pm0.2)\,$eV, respectively. Helium-3 spin-echo measurements showed no decay of the spatial correlation function (or intermediate scattering function) within the time range of the spectrometer. Hence, we are able to set lower limits for a possible hydrogen surface diffusion rate.