Consistency of the structure of Legendre transform in thermodynamics with the Kolmogorov-Nagumo average

A. M. Scarfone, H. Matsuzoe, T. Wada

Published 2022-06-09Version 1

We show the robustness of the structure of Legendre transform in thermodynamics against the replacement of the standard linear average with the Kolmogorov-Nagumo nonlinear average to evaluate the expectation values of the macroscopic physical observables. The consequence of this statement is twofold: 1) the relationships between the expectation values and the corresponding Lagrange multipliers still hold in the present formalism; 2) the universality of the Gibbs equation as well as other thermodynamic relations are unaffected by the structure of the average used in the theory.