One-step fabrication of metal nanostructures by high-throughput imprinting

Ze Liu

Published 2016-11-10Version 1

Direct nanoimprinting provides a simple and high-throughput route for producing uniform nanopatterns at great precision and at low costs. However, applying this technique to crystalline metals has been considered as impossible due to intrinsic limitation from grain size effect. Here we demonstrate direct superplastic nanoimprinting (SPNI) of crystalline metals well below their melting temperatures (Tm), generating ordered nanowire arrays with aspect ratio up to ~2000. Our investigations of replicating metal hierarchical nanostructures show the capability of imprinting features as small as 8 nm, far smaller than the grain size of bulk metals. Most surprisingly, the prepared metal hierarchical nanostructures were found possessing perfect monocrystalline structures. These findings indicate that nanoimprinting of crystalline metals below Tm might be from lattice diffusion. SPNI as a one-step and highly controlled high-throughput fabrication method, could facilitate the applications of metal nanostructures in bio-sensing, diagnostic imaging, catalysis, food industry and environmental conservation.