Thermodynamics and the structure of quantum theory

Marius Krumm, Howard Barnum, Jonathan Barrett, Markus P. Mueller

Published 2016-08-16Version 1

Despite its enormous empirical success, the formalism of quantum theory still raises fundamental questions: why is nature described in terms of complex Hilbert spaces, and what modifications of it could we reasonably expect to find in some regimes of physics? Results in quantum gravity and general ideas of what a fundamental theory should look like suggest that thermodynamics plays a major role in the foundations of physics. In this paper, we address the question of which parts of quantum theory are already determined by compatibility with thermodynamics, and which aspects may still admit modification. We employ two postulates that any probabilistic theory with reasonable thermodynamic behavior should arguably satisfy. In the framework of generalized probabilistic theories, we show that these postulates already imply important aspects of quantum theory, like self-duality and analogues of projective measurements, subspaces and eigenvalues. However, they may still admit a class of theories beyond quantum mechanics. Using a thought experiment by von Neumann, we show that these theories admit a consistent thermodynamic notion of entropy, and prove that the second law holds for projective measurements and mixing procedures. Furthermore, we generalize the concept of state majorization, crucial to recent work in fine-grained quantum thermodynamics, to this class of theories, study additional entropy-like quantities based on measurement probabilities and convex decomposition probabilities, and uncover a relation between one of these quantities and Sorkin's notion of higher-order interference.