Inconsistent thermostatistics and negative absolute temperatures

Jörn Dunkel, Stefan Hilbert

Published 2013-04-07Version 1

A considerable body of experimental and theoretical work claims the existence of negative absolute temperatures in spin systems and ultra-cold quantum gases. Here, we clarify that such findings can be attributed to the use of a popular yet inconsistent entropy definition, which violates fundamental thermodynamic relations and fails to produce sensible results for simple analytically tractable classical and quantum systems. Within a mathematically consistent thermodynamic formalism, based on an entropy concept originally derived by Gibbs, absolute temperature remains positive even for systems with bounded spectrum. We address spurious arguments against the Gibbs formalism and comment briefly on heat engines with efficiencies greater than one.