Grand potential in thermodynamics of solid bodies and surfaces

A. I. Rusanov, A. K. Shchekin, D. V. Tatyanenko

Published 2009-10-08Version 1

Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic potential for solids has been suggested. This allows generalizing the definition of Gibbs' quantity $\sigma$ (surface work often called the solid-fluid interfacial free energy) at a planar surface as an excess grand thermodynamic potential per unit surface area that (1) does not depend on the dividing surface location and (2) is common for fluids and solids.