{
  "id": "cond-mat/0506231",
  "version": "v1",
  "published": "2005-06-09T16:35:52.000Z",
  "updated": "2005-06-09T16:35:52.000Z",
  "title": "The Transition State in a Noisy Environment",
  "authors": [
    "Thomas Bartsch",
    "Rigoberto Hernandez",
    "T. Uzer"
  ],
  "journal": "Phys. Rev. Lett. 95 (2005) 058301",
  "doi": "10.1103/PhysRevLett.95.058301",
  "categories": [
    "cond-mat.stat-mech"
  ],
  "abstract": "Transition State Theory overestimates reaction rates in solution because conventional dividing surfaces between reagents and products are crossed many times by the same reactive trajectory. We describe a recipe for constructing a time-dependent dividing surface free of such recrossings in the presence of noise. The no-recrossing limit of Transition State Theory thus becomes generally available for the description of reactions in a fluctuating environment.",
  "revisions": [
    {
      "version": "v1",
      "updated": "2005-06-09T16:35:52.000Z"
    }
  ],
  "analyses": {
    "keywords": [
      "noisy environment",
      "state theory overestimates reaction rates",
      "transition state theory overestimates reaction",
      "time-dependent dividing surface free"
    ],
    "tags": [
      "journal article"
    ],
    "publication": {
      "publisher": "APS",
      "journal": "Phys. Rev. Lett."
    },
    "note": {
      "typesetting": "TeX",
      "pages": 0,
      "language": "en",
      "license": "arXiv",
      "status": "editable"
    }
  }
}