{ "id": "cond-mat/0412626", "version": "v3", "published": "2004-12-22T15:45:00.000Z", "updated": "2005-09-14T09:15:55.000Z", "title": "Asymmetric Diffusion", "authors": [ "Norman Packard", "Rob Shaw" ], "comment": "17 pages, 8 figures v3: one additional figure, several additional references, conceptually unchanged", "categories": [ "cond-mat.stat-mech" ], "abstract": "Diffusion rates through a membrane can be asymmetric, if the diffusing particles are spatially extended and the pores in the membrane have asymmetric structure. This phenomenon is demonstrated here via a deterministic simulation of a two-species hard-disk gas, and via simulations of two species in Brownian motion, diffusing through a membrane that is permeable to one species but not the other. In its extreme form, this effect will rapidly seal off flow in one direction through a membrane, while allowing free flow in the other direction. The system thus relaxes to disequilibrium, with very different densities of the permeable species on each side of the membrane. A single species of appropriately shaped particles will exhibit the same effect when diffusing through appropriately shaped pores. We hypothesize that purely geometric effects discussed here may play a role in common biological contexts such as membrane ion channels.", "revisions": [ { "version": "v3", "updated": "2005-09-14T09:15:55.000Z" } ], "analyses": { "keywords": [ "asymmetric diffusion", "membrane ion channels", "two-species hard-disk gas", "asymmetric structure", "common biological contexts" ], "note": { "typesetting": "TeX", "pages": 17, "language": "en", "license": "arXiv", "status": "editable" } } }