{ "id": "cond-mat/0402521", "version": "v1", "published": "2004-02-20T13:20:42.000Z", "updated": "2004-02-20T13:20:42.000Z", "title": "The bulk viscosity of a symmetrical Lennard--Jones mixture above and at liquid--liquid coexistence: A computer simulation study", "authors": [ "Subir K. Das", "Jürgen Horbach", "Kurt Binder" ], "comment": "19 pages including 6 figures", "categories": [ "cond-mat.stat-mech" ], "abstract": "A Lennard--Jones model of a binary dense liquid (A,B) with a symmetrical miscibility gap is investigated by means of computer simulation methods. Semigrand--canonical Monte Carlo simulations yield the phase diagram in the $T$--$x$ plane ($T$: temperature, $x$: concentration of A or B particles) as well as equilibrated configurations at coexistence. Then Molecular Dynamics simulations use these configurations to determine static properties (isothermal compressibility $\\kappa_T$ and concentration susceptibility $\\chi$) as well as the shear and the bulk viscosity $\\eta_{\\rm s}$ and $\\eta_{\\rm B}$, respectively. The latter quantities are calculated along a path approaching the coexistence line from high temperatures in the one--phase region and ending at a state at the coexistence line about 15% below the critical point. We find that $\\kappa_T$ and $\\chi$ increase significantly near the coexistence line reflecting the vicinity of the critical point. Whereas $\\eta_{\\rm s}$ exhibits a weak temperature dependence, $\\eta_{\\rm B}$ increases significantly near the coexistence curve.", "revisions": [ { "version": "v1", "updated": "2004-02-20T13:20:42.000Z" } ], "analyses": { "keywords": [ "computer simulation study", "symmetrical lennard-jones mixture", "bulk viscosity", "liquid-liquid coexistence", "coexistence line" ], "note": { "typesetting": "TeX", "pages": 19, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2004cond.mat..2521D" } } }