{ "id": "cond-mat/0301088", "version": "v2", "published": "2003-01-08T04:00:55.000Z", "updated": "2003-02-27T10:49:06.000Z", "title": "Contributions of steady heat conduction to the rate of chemical reaction", "authors": [ "Kim Hyeon-Deuk", "Hisao Hayakawa" ], "comment": "12 pages including 2 figures and 3 tables, to be published in Chemical Physics Letters", "journal": "Chem.Phys.Lett., Vol.372, No. 3-4, pp.314-319(2003)", "doi": "10.1063/1.1764089", "categories": [ "cond-mat.stat-mech" ], "abstract": "We have derived the effect of steady heat flux on the rate of chemical reaction based on the line-of-centers model using the explicit velocity distribution function of the steady-state Boltzmann equation for hard-sphere molecules to second order. It is found that the second-order velocity distribution function plays an essential role for the calculation of it. We have also compared our result with those from the steady-state Bhatnagar-Gross-Krook(BGK) equation and information theory, and found no qualitative differences among them.", "revisions": [ { "version": "v2", "updated": "2003-02-27T10:49:06.000Z" } ], "analyses": { "subjects": [ "82.20.Pm", "82.70.-y" ], "keywords": [ "steady heat conduction", "chemical reaction", "second-order velocity distribution function plays", "explicit velocity distribution function", "contributions" ], "tags": [ "journal article" ], "note": { "typesetting": "TeX", "pages": 12, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2004AIPC..708..132H" } } }