{ "id": "cond-mat/0005160", "version": "v1", "published": "2000-05-09T19:14:11.000Z", "updated": "2000-05-09T19:14:11.000Z", "title": "Entropy, Dynamics and Instantaneous Normal Modes in a Random Energy Model", "authors": [ "Tom Keyes" ], "doi": "10.1103/PhysRevE.62.7905", "categories": [ "cond-mat.stat-mech" ], "abstract": "It is shown that the fraction f of imaginary frequency instantaneous normal modes (INM) may be defined and calculated in a random energy model(REM) of liquids. The configurational entropy S and the averaged hopping rate among the states R are also obtained and related to f, with the results R~f and S=a+b*ln(f). The proportionality between R and f is the basis of existing INM theories of diffusion, so the REM further confirms their validity. A link to S opens new avenues for introducing INM into dynamical theories. Liquid 'states' are usually defined by assigning a configuration to the minimum to which it will drain, but the REM naturally treats saddle-barriers on the same footing as minima, which may be a better mapping of the continuum of configurations to discrete states. Requirements of a detailed REM description of liquids are discussed.", "revisions": [ { "version": "v1", "updated": "2000-05-09T19:14:11.000Z" } ], "analyses": { "keywords": [ "random energy model", "imaginary frequency instantaneous normal modes", "configurational entropy", "rem description" ], "tags": [ "journal article" ], "publication": { "publisher": "APS", "journal": "Phys. Rev. E" }, "note": { "typesetting": "TeX", "pages": 0, "language": "en", "license": "arXiv", "status": "editable" } } }