{ "id": "2304.13873", "version": "v1", "published": "2023-04-26T23:40:28.000Z", "updated": "2023-04-26T23:40:28.000Z", "title": "Chemical Differentiation around Five Massive Protostars Revealed by ALMA -Carbon-Chain Species, Oxygen-/Nitrogen-Bearing Complex Organic Molecules-", "authors": [ "Kotomi Taniguchi", "Liton Majumdar", "Paola Caselli", "Shigehisa Takakuwa", "Tien-Hao Hsieh", "Masao Saito", "Zhi-Yun Li", "Kazuhito Dobashi", "Tomomi Shimoikura", "Fumitaka Nakamura", "Jonathan C. Tan", "Eric Herbst" ], "comment": "Accepted by the publication for The Astrophysical Journal Supplement Series, 32 pages,18 figures, 11 tables", "categories": [ "astro-ph.GA", "astro-ph.SR" ], "abstract": "We present Atacama Large Millimeter/submillimeter Array Band 3 data toward five massive young stellar objects (MYSOs), and investigate relationships between unsaturated carbon-chain species and saturated complex organic molecules (COMs). An HC$_{5}$N ($J=35-34$) line has been detected from three MYSOs, where nitrogen(N)-bearing COMs (CH$_{2}$CHCN and CH$_{3}$CH$_{2}$CN) have been detected. The HC$_{5}$N spatial distributions show compact features and match with a methanol (CH$_{3}$OH) line with an upper-state energy around 300 K, which should trace hot cores. The hot regions are more extended around the MYSOs where N-bearing COMs and HC$_{5}$N have been detected compared to two MYSOs without these molecular lines, while there are no clear differences in the bolometric luminosity and temperature. We run chemical simulations of hot-core models with a warm-up stage, and compare with the observational results. The observed abundances of HC$_{5}$N and COMs show good agreements with the model at the hot-core stage with temperatures above 160 K. These results indicate that carbon-chain chemistry around the MYSOs cannot be reproduced by warm carbon-chain chemistry, and a new type of carbon-chain chemistry occurs in hot regions around MYSOs.", "revisions": [ { "version": "v1", "updated": "2023-04-26T23:40:28.000Z" } ], "analyses": { "keywords": [ "oxygen-/nitrogen-bearing complex organic", "carbon-chain species", "chemical differentiation", "massive protostars", "carbon-chain chemistry" ], "note": { "typesetting": "TeX", "pages": 32, "language": "en", "license": "arXiv", "status": "editable" } } }