{
  "id": "2110.13462",
  "version": "v2",
  "published": "2021-10-26T07:51:20.000Z",
  "updated": "2022-01-17T10:48:33.000Z",
  "title": "Charge and Spin Dynamics and Enantioselectivity in Chiral Molecules",
  "authors": [
    "J. Fransson"
  ],
  "comment": "Seven pages, three figures; J. Phys. Chem. Lett (2022)",
  "doi": "10.1021/acs.jpclett.1c03925",
  "categories": [
    "cond-mat.mes-hall",
    "cond-mat.soft"
  ],
  "abstract": "Charge and spin dynamics is addressed in chiral molecules immediately after the instantaneous coupling to an external metallic reservoir. It is shown how a spin-polarization is induced in the chiral structure as a response to the charge dynamics. The dynamics indicate that chiral induced spin selectivity is an excited states phenomenon which, in the transient regime partly can be captured using a simplistic single particle description, however, in the stationary limit definitively shows that electron correlations, e.g., electron-vibration interactions, crucially contribute to sustain an intrinsic spin anisotropy that can lead to a non-vanishing spin selectivity. The dynamics, moreover, provide insight to enantiomer separation, due to different acquired spin-polarizations.",
  "revisions": [
    {
      "version": "v2",
      "updated": "2022-01-17T10:48:33.000Z"
    }
  ],
  "analyses": {
    "keywords": [
      "chiral molecules",
      "spin dynamics",
      "enantioselectivity",
      "simplistic single particle description",
      "external metallic reservoir"
    ],
    "tags": [
      "journal article"
    ],
    "publication": {
      "publisher": "ACS"
    },
    "note": {
      "typesetting": "TeX",
      "pages": 0,
      "language": "en",
      "license": "arXiv",
      "status": "editable"
    }
  }
}