{ "id": "2103.03306", "version": "v1", "published": "2021-03-04T20:23:10.000Z", "updated": "2021-03-04T20:23:10.000Z", "title": "Temperature as perturbation in quantum mechanics", "authors": [ "Ashkan Shekaari", "Mahmoud Jafari" ], "categories": [ "quant-ph", "cond-mat.stat-mech" ], "abstract": "The perturbative approach was adopted to develop a temperature-dependent version of non-relativistic quantum mechanics in the limit of low-enough temperatures. A generalized, self-consistent Hamiltonian was therefore constructed for an arbitrary quantum-mechanical system in a way that the ground-state Hamiltonian turned out to be just a limiting case at absolute zero. The weak-coupling term connecting the system of interest and its immediate environment was accordingly treated as the perturbation. Applying the obtained generalized Hamiltonian to some typical quantum systems with exact zero-temperature solutions, including the free particle in a box, the free particle in vacuum, and the harmonic oscillator, up to the first order of self-consistency, therefore corrected their associated Hamiltonians, energy spectrums, and wavefunctions to be consistent with the low-temperature limit. Further investigation revealed some kind of quantum tunneling effect by a residual probability for the free particle in a box, as a chief consequence of thermally coupling to the reservoir. The possible effects of thermal environment on the main properties of the wavefunctions were also thoroughly examined and discussed.", "revisions": [ { "version": "v1", "updated": "2021-03-04T20:23:10.000Z" } ], "analyses": { "keywords": [ "free particle", "perturbation", "non-relativistic quantum mechanics", "exact zero-temperature solutions", "main properties" ], "note": { "typesetting": "TeX", "pages": 0, "language": "en", "license": "arXiv", "status": "editable" } } }