{ "id": "2001.03007", "version": "v1", "published": "2020-01-09T14:20:29.000Z", "updated": "2020-01-09T14:20:29.000Z", "title": "Fastest Frozen Temperature for a Degree of Freedom", "authors": [ "X. Y. Zhou", "Z. Q. Yang", "X. R. Tang", "X. Wang", "Q. H. Liu" ], "comment": "6 pages, 4 figures", "categories": [ "cond-mat.stat-mech", "quant-ph" ], "abstract": "The equipartition theorem states that the mean thermal energy for each degree of freedom at a temperature $T$ is given by $k_{B}T/2$ where $k_{B}$ is Boltzmann's constant. However, this theorem for the degree of freedom breaks down at lower enough temperature when the relevant degree of freedom is not thermally excited. The frozen condition can be \\textit{qualitatively} expressed as $T\\ll T_{C}$ which is the characteristic temperature defined via $k_{B}T_{C}\\equiv\\varepsilon_{1}-\\varepsilon_{0}$ in which $\\varepsilon_{0}$ and $\\varepsilon_{1}$ are, respectively, the ground state and first excited energy of the degree of freedom. This characteristic temperature $T_{C}$ so defined is the temperature at which the degree of freedom is almost activated. We report that there is a well-defined temperature at which the specific heat coming from the given degree of freedom \\textit{changes most dramatically} with temperature, i.e., the derivative of the specific heat with respect to temperature reaches its maximum. For some system such as a mixture of ortho- and para- hydrogen molecules, the characteristic temperature is hard to define, the fastest frozen temperature is also straightforward and well-defined. In general, the fastest frozen temperature is a \\emph{quantitative}\\textit{\\ }criterion of the frozen temperature.", "revisions": [ { "version": "v1", "updated": "2020-01-09T14:20:29.000Z" } ], "analyses": { "keywords": [ "fastest frozen temperature", "characteristic temperature", "specific heat", "mean thermal energy", "equipartition theorem states" ], "note": { "typesetting": "TeX", "pages": 6, "language": "en", "license": "arXiv", "status": "editable" } } }