{ "id": "1807.02539", "version": "v1", "published": "2018-07-06T18:33:59.000Z", "updated": "2018-07-06T18:33:59.000Z", "title": "Substitutional mechanism for growth of hexagonal boron nitride on epitaxial graphene", "authors": [ "Patrick C. Mende", "Jun Li", "Randall M. Feenstra" ], "comment": "9 pages (with 3 figures), plus 9 pages of Supplementary Material (with 7 figures)", "categories": [ "cond-mat.mes-hall" ], "abstract": "Monolayer-thick hexagonal boron nitride (h-BN) is grown on graphene on SiC(0001), by exposure of the graphene to borazine, (BH)3(NH)3, at 1100 C. The h-BN films form ~2-micrometer size grains with a preferred orientation of 30 degrees relative to the surface graphene. Low-energy electron microscopy is employed to provide definitive signatures of the number and composition of two-dimensional (2D) planes across the surface. These grains are found to form by substitution for the surface graphene, with the C atoms produced by this substitution then being incorporated below the h-BN (at the interface between the existing graphene and the SiC) to form a new graphene plane.", "revisions": [ { "version": "v1", "updated": "2018-07-06T18:33:59.000Z" } ], "analyses": { "keywords": [ "epitaxial graphene", "substitutional mechanism", "monolayer-thick hexagonal boron nitride", "surface graphene", "low-energy electron microscopy" ], "note": { "typesetting": "TeX", "pages": 9, "language": "en", "license": "arXiv", "status": "editable" } } }