{ "id": "1704.02662", "version": "v1", "published": "2017-04-09T21:19:17.000Z", "updated": "2017-04-09T21:19:17.000Z", "title": "How to determine a boundary condition at a thin membrane for diffusion from experimental data", "authors": [ "Tadeusz Kosztołowicz", "Sławomir Wąsik", "Katarzyna D. Lewandowska" ], "comment": "4 pages, 4 figures", "categories": [ "cond-mat.stat-mech" ], "abstract": "We present a new method of deriving a boundary condition at a thin membrane for diffusion from experimental data. Based on experimental results obtained for normal diffusion of ethanol in water, we show that the derived boundary condition at a membrane contains a term with the Riemann--Liouville fractional time derivative of the $1/2$ order. Such a form of the boundary condition shows that a transfer of particles through a thin membrane is a `long memory process'. Presented method is an example that an important part of mathematical model of physical process may be derived directly from experimental data.", "revisions": [ { "version": "v1", "updated": "2017-04-09T21:19:17.000Z" } ], "analyses": { "keywords": [ "thin membrane", "experimental data", "long memory process", "important part", "normal diffusion" ], "note": { "typesetting": "TeX", "pages": 4, "language": "en", "license": "arXiv", "status": "editable" } } }