{ "id": "1702.01010", "version": "v1", "published": "2017-02-03T14:03:19.000Z", "updated": "2017-02-03T14:03:19.000Z", "title": "Variation along liquid isomorphs of the driving force for crystallization", "authors": [ "Ulf R. Pedersen", "Karolina Adrjanowicz", "Kristine Niss", "Nicholas P. Bailey" ], "comment": "Submission to SciPost", "categories": [ "cond-mat.stat-mech", "cond-mat.mtrl-sci" ], "abstract": "We investigate the variation of the driving force for crystallization of a supercooled liquid along isomorphs, curves along which structure and dynamics are invariant. The variation is weak, and can be predicted accurately for the Lennard-Jones fluid using a recently developed formalism and data at a reference temperature. More general analysis allows interpretation of experimental data for molecular liquids such as dimethyl phthalate and indomethacin, and suggests that the isomorph scaling exponent $\\gamma$ in these cases is an increasing function of density, although this cannot be seen in measurements of viscosity or relaxation time.", "revisions": [ { "version": "v1", "updated": "2017-02-03T14:03:19.000Z" } ], "analyses": { "keywords": [ "driving force", "liquid isomorphs", "crystallization", "isomorph scaling exponent", "general analysis" ], "note": { "typesetting": "TeX", "pages": 0, "language": "en", "license": "arXiv", "status": "editable" } } }