{ "id": "1507.02305", "version": "v1", "published": "2015-07-08T20:44:50.000Z", "updated": "2015-07-08T20:44:50.000Z", "title": "Topological Constraints in Directed Polymer Melts", "authors": [ "Pablo Serna", "Guy Bunin", "Adam Nahum" ], "categories": [ "cond-mat.stat-mech", "cond-mat.soft", "physics.bio-ph" ], "abstract": "Polymers in a melt may be subject to topological constraints, as in the example of unlinked polymer rings. How to do statistical mechanics in the presence of such constraints remains a fundamental open problem. We study the effect of topological constraints on a melt of directed polymers using simulations of a simple quasi-2D model. We find that fixing the global topology of the melt to be trivial changes the polymer conformations drastically. Polymers of length $L$ wander in the transverse direction only by a distance of order $(\\ln L)^\\zeta$ with $\\zeta \\simeq 1.5$. This is strongly suppressed in comparison with the Brownian scaling $L^{1/2}$ which holds in the absence of the topological constraint. It is also much less than the prediction $L^{1/4}$ of a mean-field-like `array of obstacles' model: thus we rule out such a model in the present setting. Dynamics are also strongly affected by the constraints, and a tagged monomer in an infinite system performs logarithmically slow subdiffusion. To cast light on the suppression of the strands' wandering, we analyse the topological complexity of subregions of the melt: the complexity is also logarithmically small, and is related to the wandering by a power law. We comment on insights the results give for 3D melts, directed and non-directed.", "revisions": [ { "version": "v1", "updated": "2015-07-08T20:44:50.000Z" } ], "analyses": { "keywords": [ "topological constraint", "directed polymer melts", "infinite system performs logarithmically slow", "system performs logarithmically slow subdiffusion", "fundamental open problem" ], "note": { "typesetting": "TeX", "pages": 0, "language": "en", "license": "arXiv", "status": "editable" } } }