{ "id": "1411.3644", "version": "v1", "published": "2014-11-13T18:10:22.000Z", "updated": "2014-11-13T18:10:22.000Z", "title": "Emergent rhombus tilings from molecular interactions with $M$-fold rotational symmetry", "authors": [ "Stephen Whitelam", "Isaac Tamblyn", "Juan P. Garrahan", "Peter H. Beton" ], "categories": [ "cond-mat.stat-mech", "cond-mat.soft" ], "abstract": "We show that model molecules with particular rotational symmetries can self-assemble into network structures equivalent to rhombus tilings. This assembly happens in an emergent way, in the sense that molecules spontaneously select irregular 4-fold local coordination from a larger set of possible local binding geometries. The existence of such networks can be rationalized by simple geometrical arguments, but the same arguments do not guarantee networks' spontaneous self-assembly. This class of structures must in certain regimes of parameter space be able to reconfigure into networks equivalent to triangular tilings.", "revisions": [ { "version": "v1", "updated": "2014-11-13T18:10:22.000Z" } ], "analyses": { "subjects": [ "64.75.Yz", "05.70.Fh", "81.16.Fg" ], "keywords": [ "emergent rhombus tilings", "fold rotational symmetry", "molecular interactions", "network structures equivalent", "molecules spontaneously select irregular" ], "tags": [ "journal article" ], "publication": { "doi": "10.1103/PhysRevLett.114.115702", "journal": "Physical Review Letters", "year": 2015, "month": "Mar", "volume": 114, "number": 11, "pages": 115702 }, "note": { "typesetting": "TeX", "pages": 0, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2015PhRvL.114k5702W" } } }