{ "id": "1411.2425", "version": "v1", "published": "2014-11-10T13:45:55.000Z", "updated": "2014-11-10T13:45:55.000Z", "title": "Uniqueness of Gibbs entropy within the microcanonical formalism", "authors": [ "Michele Campisis" ], "comment": "4 pages", "categories": [ "cond-mat.stat-mech" ], "abstract": "It is a well known fact that, within the classical microcanonical formalism, the Gibbs entropy (alias volume entropy) is a thermodynamically consistent expression of entropy. Building on the concept of uniqueness of Clausius integrating factor for the inexact heat differential (i.e., the existence of a universal temperature scale) here we show that Gibbs entropy is the unique consistent expression. As a consequence negative temperatures are inadmissible within the classical microcanonical formalism.", "revisions": [ { "version": "v1", "updated": "2014-11-10T13:45:55.000Z" } ], "analyses": { "subjects": [ "05.70.-a", "05.20.-y", "05.30.-d" ], "keywords": [ "gibbs entropy", "uniqueness", "classical microcanonical formalism", "inexact heat differential", "universal temperature scale" ], "publication": { "doi": "10.1103/PhysRevE.91.052147", "journal": "Physical Review E", "year": 2015, "month": "May", "volume": 91, "number": 5, "pages": "052147" }, "note": { "typesetting": "TeX", "pages": 4, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2015PhRvE..91e2147C" } } }