{ "id": "1410.2524", "version": "v1", "published": "2014-10-09T16:38:03.000Z", "updated": "2014-10-09T16:38:03.000Z", "title": "Field-enhanced recombination at low temperatures in an organic photovoltaic blend", "authors": [ "S. Athanasopoulos", "N. C. Greenham", "R. H. Friend", "A. D. Chepelianskii" ], "categories": [ "cond-mat.mes-hall" ], "abstract": "We report on the non-trivial field dependence of charge carrier recombination in an organic blend at low temperatures. A new microwave resonance technique for monitoring charge recombination in organic semiconductors at low temperatures is applied in bulk heterojunction P3HT:PCBM blends with results showing that an external electric field can in fact increase recombination. Monte Carlo simulations suggest that this contradiction to conventional wisdom relates to electron-hole pairs that are separated at donor-acceptor interfaces where the electric field acts in synergy with their Coulomb attraction. For this behaviour to occur a critical initial separation of 5nm between the carriers is required.", "revisions": [ { "version": "v1", "updated": "2014-10-09T16:38:03.000Z" } ], "analyses": { "subjects": [ "73.63.-b", "73.50.Pz", "74.78.Na" ], "keywords": [ "low temperatures", "organic photovoltaic blend", "field-enhanced recombination", "microwave resonance technique", "non-trivial field dependence" ], "publication": { "doi": "10.1103/PhysRevB.92.125301", "journal": "Physical Review B", "year": 2015, "month": "Sep", "volume": 92, "number": 12, "pages": 125301 }, "note": { "typesetting": "TeX", "pages": 0, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2015PhRvB..92l5301A" } } }