{ "id": "1307.5532", "version": "v3", "published": "2013-07-21T15:32:03.000Z", "updated": "2014-11-05T20:15:07.000Z", "title": "Quantum entanglement for two electrons in the excited states of helium-like systems", "authors": [ "Yen-Chang Lin", "Yew Kam Ho" ], "comment": "Final version to be published in Canadian Journal of Physics; more references added; more tables added; discussion expanded", "categories": [ "quant-ph", "physics.atom-ph" ], "abstract": "The quantum entanglement for the two electrons in the excited states of the helium-like atom/ions is investigated using the two-electron wave functions constructed by the B-spline basis. As a measure of the spatial (electron-electron orbital) entanglement, the von Neumann entropy and linear entropy of the reduced density matrix are calculated for the 1s2s 1,3S excited states for systems with some selected Z values from Z=2 to Z=100. Results for the helium atom are compared with other available calculations. We have also investigated the entropies for these excited states when the nucleus charge is reduced from Z=2 to Z=1. At such a critical charge, all the singly-excited states of this system become unbound, and the linear entropies and the von Neumann entropies for the excited states are approaching 1/2 and 1, respectively, the limits for the entropies when one electron is bound to the nucleus, and the other being free.", "revisions": [ { "version": "v2", "updated": "2014-08-09T09:09:22.000Z", "comment": "15 pages, 3 figures, recent references added; discussion expanded; appendix A added", "journal": null, "doi": null }, { "version": "v3", "updated": "2014-11-05T20:15:07.000Z" } ], "analyses": { "keywords": [ "quantum entanglement", "helium-like systems", "von neumann entropy", "linear entropy", "two-electron wave functions" ], "publication": { "doi": "10.1139/cjp-2014-0437", "journal": "Canadian Journal of Physics", "year": 2015, "month": "Jun", "volume": 93, "number": 6, "pages": 646 }, "note": { "typesetting": "TeX", "pages": 15, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2015CaJPh..93..646L" } } }