{ "id": "1108.5680", "version": "v1", "published": "2011-08-29T18:08:06.000Z", "updated": "2011-08-29T18:08:06.000Z", "title": "Potential and Flux Decomposition for Dynamical Systems and Non-Equilibrium Thermodynamics: Curvature, Gauge Field and Generalized Fluctuation-Dissipation Theorem", "authors": [ "Haidong Feng", "Jin Wang" ], "categories": [ "cond-mat.stat-mech", "physics.chem-ph" ], "abstract": "The driving force of the dynamical system can be decomposed into the gradient of a potential landscape and curl flux (current). The fluctuation-dissipation theorem (FDT) is often applied to near equilibrium systems with detailed balance. The response due to a small perturbation can be expressed by a spontaneous fluctuation. For non-equilibrium systems, we derived a generalized FDT that the response function is composed of two parts: (1) a spontaneous correlation representing the relaxation which is present in the near equilibrium systems with detailed balance; (2) a correlation related to the persistence of the curl flux in steady state, which is also in part linked to a internal curvature of a gauge field. The generalized FDT is also related to the fluctuation theorem. In the equal time limit, the generalized FDT naturally leads to non-equilibrium thermodynamics where the entropy production rate can be decomposed into spontaneous relaxation driven by gradient force and house keeping contribution driven by the non-zero flux that sustains the non-equilibrium environment and breaks the detailed balance.", "revisions": [ { "version": "v1", "updated": "2011-08-29T18:08:06.000Z" } ], "analyses": { "subjects": [ "05.70.Ln", "11.15.-q", "05.40.-a", "05.70.Ce" ], "keywords": [ "generalized fluctuation-dissipation theorem", "non-equilibrium thermodynamics", "gauge field", "dynamical system", "flux decomposition" ], "tags": [ "journal article" ], "publication": { "doi": "10.1063/1.3669448", "journal": "Journal of Chemical Physics", "year": 2011, "month": "Dec", "volume": 135, "number": 23, "pages": 4511 }, "note": { "typesetting": "TeX", "pages": 0, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2011JChPh.135w4511F" } } }