{ "id": "1010.6047", "version": "v1", "published": "2010-10-28T18:49:04.000Z", "updated": "2010-10-28T18:49:04.000Z", "title": "Electronic states and optical properties of PbSe nanorods and nanowires", "authors": [ "A. C. Bartnik", "Al. L. Efros", "W. -K. Koh", "C. B. Murray", "F. W. Wise" ], "comment": "35 pages, 12 figures", "categories": [ "cond-mat.mes-hall" ], "abstract": "A theory of the electronic structure and excitonic absorption spectra of PbS and PbSe nanowires and nanorods in the framework of a four-band effective mass model is presented. Calculations conducted for PbSe show that dielectric contrast dramatically strengthens the exciton binding in narrow nanowires and nanorods. However, the self-interaction energies of the electron and hole nearly cancel the Coulomb binding, and as a result the optical absorption spectra are practically unaffected by the strong dielectric contrast between PbSe and the surrounding medium. Measurements of the size-dependent absorption spectra of colloidal PbSe nanorods are also presented. Using room-temperature energy-band parameters extracted from the optical spectra of spherical PbSe nanocrystals, the theory provides good quantitative agreement with the measured spectra.", "revisions": [ { "version": "v1", "updated": "2010-10-28T18:49:04.000Z" } ], "analyses": { "subjects": [ "73.21.Hb", "73.22.Dj", "78.67.Lt" ], "keywords": [ "electronic states", "optical properties", "dielectric contrast dramatically strengthens", "excitonic absorption spectra", "four-band effective mass model" ], "tags": [ "journal article" ], "publication": { "doi": "10.1103/PhysRevB.82.195313", "journal": "Physical Review B", "year": 2010, "month": "Nov", "volume": 82, "number": 19, "pages": 195313 }, "note": { "typesetting": "TeX", "pages": 35, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2010PhRvB..82s5313B" } } }