{ "id": "1005.1251", "version": "v2", "published": "2010-05-07T17:00:56.000Z", "updated": "2011-02-02T17:02:30.000Z", "title": "Thermodynamics of Markov Processes with Non-extensive Entropy and Free Energy", "authors": [ "Hong Qian" ], "comment": "6 pages", "categories": [ "math-ph", "math.MP" ], "abstract": "Parallel to the recent presented complete thermodynamic formalism for master equation systems, we show that a \"thermodynamic\" theory can also be developed based on Tsallis' generalized entropy $S_q and Shiino's generalized free energy F_q which depends on \\pi_i, the stationary distribution of the master equation. $dF_q/dt=-f_d\\le 0$ and it is zero iff the system is in its stationary state. $dS_q/dt = f_d-Q_{ex}$ where $Q_{ex}$ characterizes the heat exchange. For systems approaching equilibrium with detailed balance, $f_d$ is the product of Onsager's thermodynamic flux and force. However, it is discovered that the Onsager's force is non-local. This is a consequence of the particular transformation invariance for zero energy of Tsallis' statistics.", "revisions": [ { "version": "v2", "updated": "2011-02-02T17:02:30.000Z" } ], "analyses": { "keywords": [ "free energy", "markov processes", "non-extensive entropy", "master equation systems", "complete thermodynamic formalism" ], "note": { "typesetting": "TeX", "pages": 6, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2010arXiv1005.1251Q" } } }