{ "id": "0905.0800", "version": "v1", "published": "2009-05-06T10:51:50.000Z", "updated": "2009-05-06T10:51:50.000Z", "title": "The Effects of Molecular Anions on the Chemistry of Dark Clouds", "authors": [ "Catherine Walsh", "Nanase Harada", "Eric Herbst", "T. J. Millar" ], "comment": "Accepted for publication in ApJ, 24 pages, 5 figures", "journal": "Astrophys.J.700:752-761,2009", "doi": "10.1088/0004-637X/700/1/752", "categories": [ "astro-ph.GA" ], "abstract": "We have investigated the role of molecular anion chemistry in pseudo-time dependent chemical models of dark clouds. With oxygen-rich elemental abundances, the addition of anions results in a slight improvement in the overall agreement between model results and observations of molecular abundances in TMC-1 (CP). More importantly, with the inclusion of anions, we see an enhanced production efficiency of unsaturated carbon-chain neutral molecules, especially in the longer members of the families CnH, CnH2, and HCnN. The use of carbon-rich elemental abundances in models of TMC-1 (CP) with anion chemistry worsens the agreement with observations obtained in the absence of anions.", "revisions": [ { "version": "v1", "updated": "2009-05-06T10:51:50.000Z" } ], "analyses": { "keywords": [ "dark clouds", "carbon-rich elemental abundances", "pseudo-time dependent chemical models", "oxygen-rich elemental abundances", "molecular anion chemistry" ], "tags": [ "journal article" ], "publication": { "journal": "The Astrophysical Journal", "year": 2009, "month": "Jul", "volume": 700, "number": 1, "pages": 752 }, "note": { "typesetting": "TeX", "pages": 24, "language": "en", "license": "arXiv", "status": "editable", "inspire": 819546, "adsabs": "2009ApJ...700..752W" } } }