{ "id": "0808.3271", "version": "v1", "published": "2008-08-24T20:58:35.000Z", "updated": "2008-08-24T20:58:35.000Z", "title": "Reply to Comment on \"Failure of the work-Hamiltonian connection for free-energy calculations\" by Horowitz and Jarzynski", "authors": [ "J. M. G. Vilar", "J. M. Rubi" ], "comment": "To appear in Physical Review Letters", "categories": [ "cond-mat.stat-mech" ], "abstract": "We show that the Comment [arXiv:0808.1224] by Horowitz and Jarzynski obtains as a main result a general free energy change for a harmonic system that in the macroscopic limit does not recover the textbook expression for the energy change of a Hookean spring. The reason is that Horowitz and Jarzynski improperly identify work with parametric changes of the Hamiltonian instead of with the standard quantity, force times displacement.", "revisions": [ { "version": "v1", "updated": "2008-08-24T20:58:35.000Z" } ], "analyses": { "keywords": [ "work-hamiltonian connection", "free-energy calculations", "general free energy change", "force times displacement", "main result" ], "note": { "typesetting": "TeX", "pages": 0, "language": "en", "license": "arXiv", "status": "editable", "adsabs": "2008arXiv0808.3271V" } } }